Many things can increase the TVOC readings. Cooking in the house, using hand sanitizer near the sensor. I haven’t noticed a regular spike when I 3d print, so can’t say if that should always register, especially with PLA.
CO2 isn’t necessarily uncalibrated, but it is calibrating once a week to the lowest level. If you know, or suspect, that you may not get that low in a week, then you can take it outside for 5 minutes, run the process to do a manual calibration, wait 3 minutes, and then disable the automatic calibration, and you should be mostly set.
I did read that moving the sensors around, such as shipping them, can throw off the calibration and is part of why the automatic is running. I don’t move mine much, so once I calibrate outside, I gently move it inside and let it sit.
To be clear, this isn’t something specific to AirGradient or even the SenseAir S8 module being used, but I’ve seen other CO2 sensors do automatic calibrations like this, so being aware and choosing how to handle it is part of the open nature